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POST a QUESTION or COMMENT about plastic PVC pipe properties, uses, inspection, defects, inspection, standards, failures
PVC or chlorinated polyvinyl chloride plastic plumbing pipes:
This article series describes the properties of polubutylene PVC & CPVC plastic piping and tubing used in buildings. We include information about failures and problems with some generations of CPVC or PVC plastic pipes and we describe good building practice installation details where plastic piping is being installed.
The articles at this website will answer most questions about plastic building water supply and building drain piping products, failures, and claims as well as many other building plumbing system inspection or defect topics.
InspectAPedia tolerates no conflicts of interest. We have no relationship with advertisers, products, or services discussed at this website.
- Daniel Friedman, Publisher/Editor/Author - See WHO ARE WE?
We took this picture of pipes resting on a gravel driveway. This is not where this pipe will be installed.
Properties of CPVC and PVC Piping
What's the difference between PVC and CPVC plastic piping?
PVC, polyvinyl chloride plastic pipe is used in both pressure and non-pressure piping applications.
CPVC, chlorinated polyvinyl chloride pipe (shown below) is typically used for pressurized piping applications such as hot and cold potable water distribution. CPVC pipe can be used for handling corrosive liquids so is found in industrial and chemical applications.
CPVC Plastic Pipe Identifying Markings
Below we illustrate typical markings and specifications found on lengths of CPVC piping.
Chlorinated polyvinyl chloride (CPVC) pipe is not as flexible as PB or PEX and the fittings are solvent welded (glued) rather than press-on.
This pipe is likely to split if freezing occurs. - Home Reference Book, used with permission.
Watch out: PVC polyvinyl chloride pipe produced by JM Eagle Corp. is reported to be defective, leaking or breaking as early as in the first year after installation.
Watch out: Using the wrong solvent adhesive, or not using it properly (including pre-cleaning the pipe joints) not only results in leaky plumbing, also the purple solvent cement makes permanent stains, as Oatey Plumbing points out:
The pigments or dyes in Oatey Purple Primer and Oatey Purple Primer/Cleaner are permanent. Depending on the type of material stained, its porosity and the length of time the stain has set, it may be possible to remove or lighten the stain.
We recommend blotting a clean, dry towel with Oatey Clear Cleaner to attempt to remove the stain. It may not be possible to remove the colorant from particular fabrics or surfaces.
The finish and/or color of certain fabrics or materials may be dulled or discolored when in contact with solvents in Oatey Clear Cleaner.
You may want to try the cleaner on an inconspicuous spot before using on the stained area. Please use our purple primers and colored cements with caution.
PVC is Poly(Vinyl) Chloride, CPVC is Chlorinated Poly(Vinyl) Chloride and ABS is Acrylonitrile-Butadiene-Styrene. PVC and ABS pipe are normally used for drain, waste and vent (DWV) systems.
CPVC is used for water distribution systems. It is important to choose the correct solvent cement or pipe glue based on the type of plastic pipe being used.
You should not bury plastic sewer piping in sharp rocks but rather it should be bedded in sand and located 18" below the ground surface or deeper to reduce chances of damage from rocks or from vehicles passing overhead.
Below is an illustration of typical markings on PVC plastic pipe. Shwon below, white 4" Schedule 40 PVC piping meeting ASTM D2665.
Compare Schedule 40 PVC Piping with SDR 35 Piping
Reader Question: which pipe is better for a buried downspout drain line: Schedule 40 or SDR 35?
If you have a moment for a quick question.
What pipe is better for an underground rain gutter?
Schedule 40 or SDR 35?
Each gutter will drain right on top of a catch and go to day light. - Anonymous by private email 18 October 2015
Reply:
In my opinion Schedule 40 is a better choice as it's a heavier pipe less likely to be crushed by equipment driving over top of the system than SDR35 pipe.
The Schedule 40 PVC pipe will be more costly to install and (usually) requires solvent-glued connections while the SDR35 piping assembles using press-together o-ring-sealed hubs.
However Schedule 40 is not required for downspout drains anywhere that I've read and some plumbers will consider it overkill for many applications where the pipe is not exposed to damage.
White PVC Schedule 40 piping is shown above.
This piping is sold for use in both water distribution systems and for sewer and drainage systems. A lighter-weight Schedule 30 white solvent-welded PVC pipe is also available to meet ASTM D2949.
If you are installing your drain piping where vehicles heavier than a home lawnmower are going to be driving over the piping, I recommend using Schedule 80 for taht application.
Pressure-rated PVC piping (that is for pipes under pressure rather than pipes being used as a gravity drain) JM Eagle provides jpiping meeting ASTM D2241. Below I'll give a pipe and standards summary list for PVC.
Green colored SDR piping is a lighter-schedule pipe. According to JM Eagle, the company's SDR 35 and SDR 26 Ring-Tite™ hub jointed piping meets ASTM D3034 and the company's PS46 and PS115 meet ASTM standard F679. These PVC pipes are sold for use in gravity sewer systems.
You can take a look at pipe specifications in brochures and tables from the manufacturers to make a more factual comparison.
JM Eagle's "Gravity Sewer" piping meets ASTM D3034 and ASTM F679. The companys green PVC hub-type piping includes an O-ring to seal between joints and is intended fdor both normal residential or "domestic" sanitary sewer piping and also for certain industrial wastes.
Contact JM Eagle's customer service department for other applications or for using this pipe with specific chemicals. This pipe is sold in diameters from 4" to 36". The 4-inch pipe has an impact resistance of 150 foot pounds. 6-8" pipe of this type has an impact resistance of 210 foot pounds. The larger sizes are rated with an impact resistance of 220 foot pounds.
JM Eagle Global Headquarters, 5200 West Century Blvd
Los Angeles, CA 90045
T: 800.621.4404 , JM Eagle, Product Assurance Department: Tel: 800-621-4404 Website: www.JMEagle.com
The following data is excerpted from JM Eagle's "Solvent Weld PVC Pipe" retrieved 2015/12/14, original source: http://www.jmeagle.com/plastic-pipe/pvc-pipe/plumbing-solvent-weld.html
ASTM F679:
PS46 and PS115
Ring-Tite™ Joints 18" - 36"
Excerpt:
Gravity Sewer Pipe and Fittings
JM Eagle™ realizes the growing demand for an effective all-out attack on water pollution, highlighting the need for improved sanitary sewage collection systems.
A modern system needs pipe with improved design for reserve strength and stiffness to increase load-bearing capacity - all within the framework of maximizing sewer system capacity at a resonable cost. JM Eagle's Ring-Tite™ PVC sewer pipe is designed to meet this need. - JM Eagle Op Cit
White Solvent-Weld PVC Pipe Catalog Description
Excerpt:
Solvent weld joints are designed to provide a rigid (or restrained) joint connection.
These products are engineered for use in a variety of applications from potable water distribution to sewer and drainage systems. Additionally, the schedule rated products are specifically engineered for use in partial support systems above ground. - JM Eagle Op.CIt.
Early in 2010 New York Times reported that John Hendrix has accused PVC piping manufacturer JM Eagle of falsifying PVC pipe quality testing results, covering up the discovery that pipes that should last 50 years are failing as early as in one year, risking costly leaks and dangerous explosions.
Indeed the same Times article reported that some U.S. municipalities have already found leaking, cracking, and exploding PVC pipes made by JM Eagle, and some are joining the "whistle blower" lawsuit as a result. Litigation has been filed in the U.S. District Court for Central District of California, and has been joined by California, Delaware, Nevada, Tennessee, and Virginia. The Nevada state attorney general cited JM Eagle pipe that had been rupturing several times a year.
In April 2010, again reported in the NY Times, JM Eagle promised to guarantee its products for 50 years, including pipe that is already in the ground. "The warranty covers the pipe based on standards that were in effect at the time of the installation," the times reported. Links to and excepts from the JM Eagle pipe warranty are provided below at References.
Watch out: the same April 2010 Times article points out that municipalities had already reported pipe failures that "... may not qualify for a claim against the new guarantee..."
Research on PVC Pipe & Cement Installation, Specification, Performance
Charlotte Pipe, INSTALLING PVC PIPE in UNDERGROUND INSTALLATIONS [PDF] Charlotte Pipe & Foundry Co., Charlotte, North Carolina, USA, Web: https://www.charlottepipe.com/ - retrieved 2022/07/30, original source: https://www.charlottepipe.com/Documents/PL_Tech_Man/PVCUnderground.pdf
Excerpt: Switching a commercial plumbing system from cast iron to plastic takes more than just changing materials.
Installation requirements change, and failure to address these differences may result in your plumbing system failing.
Charlotte Pipe, PLASTIC PIPE PRESSURE & TEMPERATURE RELATIONSHIP [PDF] Charlotte Pipe & Foundry Co., Charlotte, North Carolina, USA, Web: https://www.charlottepipe.com/ retrieved 2022/07/30, original source: https://www.charlottepipe.com/TechTools/Content/temp_derating_calc_info.pdf
Hallam, N. B., J. R. West, C. F. Forster, J. C. Powell, and I2 Spencer. "The decay of chlorine associated with the pipe wall in water distribution systems." Water Research 36, no. 14 (2002): 3479-3488.
Hallam, N. B., J. R. West, C. F. Forster, and J. Simms. "The potential for biofilm growth in water distribution systems." Water Research 35, no. 17 (2001): 4063-4071.
Holsen, Thomas M., Jae Kwang Park, David Jenkins, and Robert E. Selleck. "Contamination of potable water by permeation of plastic pipe." Journal‐American Water Works Association 83, no. 8 (1991): 53-56.
Momba, Maggy NB, and N. Makala. "Comparing the effect of various pipe materials on biofilm formation in chlorinated and combined chlorine-chloraminated water systems." Water Sa 30, no. 2 (2004): 175-182.
Niquette, Patrick, Pierre Servais, and Raoul Savoir. "Impacts of pipe materials on densities of fixed bacterial biomass in a drinking water distribution system." Water research 34, no. 6 (2000): 1952-1956.
Sosebee, J. B., Paul C. Geiszler, Duane L. Winegardner, and Curtis R. Fisher. "Contamination of groundwater samples with poly (vinyl chloride) adhesives and poly (vinyl chloride) primer from monitor wells." In Hazardous and Industrial Solid Waste Testing: Second Symposium. ASTM International, 1983.
Abstract: The potential for contamination of groundwater samples by poly(vinyl chloride) (PVC) primer and adhesive was studied in both a laboratory simulation and actual groundwater samples.
Tetrahydrofuran, methylethylketone, methylisobutylketone, and cyclohexanone were identified as the major constitutents of PVC primer and adhesive, and were found to be leached into the water surrounding bonded joints. The amount of organics released to the water declined with successive washes of water.
The occurrence of such compounds can mask the presence of priority pollutants and create uncertainties in the determination of groundwater quality. Recommendations are given for the elimination or minimization of potential problems.
Tomboulian, P., L. Schweitzer, K. Mullin, J. Wilson, and D. Khiari. "Materials used in drinking water distribution systems: contribution to taste-and-odor." Water Science and Technology 49, no. 9 (2004): 219-226.
Question: solvent welded PVC pipe safe to use for water supply
2020/04/09 Neal Wilson said:
Is solvent welded PVC pipe safe to use for water supply or does it leach VOCs? Thanks.
Reply:
Neal
Thanks for asking about using PVC pipe "solvent-welded" joints on potable water supply piping.
Some (but probably not all) PVC pipe cements specifically state in their literature or even on the product label that the PVC cement is rated for use on potable PVC water supply piping.
Note: See the article we cite by Sosebee, but also, you'll see by some example research we include below, that a more-common concern with PVC piping in potable water supplies is the growth of biofilm.
Examples include
Oatey's Rain-R-Shine Blue PVC Cement
Gorilla PVC Cement
and probably at least some
Weld-On PVC cement produced by Weldon
If you are working in the U.S. you may want to see if your PVC cement complies with ASTM standards that cite "potable water" among the standard's applications, such as
ASTM D2846 / D2846M - 19a Standard Specification for Chlorinated Poly(Vinyl Chloride) (CPVC) Plastic Hot- and Cold-Water Distribution Systems
Excerpt: This specification covers requirements, test methods, and methods of marking for chlorinated poly(vinyl chloride) plastic hot- and cold-water distribution system components made in one standard dimension ratio and intended for water service up to a certain temperature.
These components comprise pipe and tubing, socket-type fittings, street fittings, plastic-to-metal transition fittings, solvent cements, and adhesives. The components are intended for use in residential and commercial, hot and cold, potable water distribution systems.
and
ASTM D2672 - 14 Standard Specification for Joints for IPS PVC Pipe Using Solvent Cement
Excerpt: This specification covers the socket produced for solvent cement joints on both pressure and non-pressure IPS pipe. It also covers the testing of the joints on both pressure and non-pressure pipe, and includes requirements for socket dimensions, burst pressure, and joint tightness tests of the solvent cemented joints.
The tests described are not intended for routine quality control, but rather to evaluate the performance characteristics of the joint.
Note 1: On dual marked Schedule 40 DWV and potable water pipe, the socket bells must conform to the dimensional and physical requirements for pressure socket bells.
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In addition to any citations in the article above, a full list is available on request.
Georg Fischer, "Design & Installation, Set & Cure Time [for solvent-cemented PVC piping glued joints]", Georg Fischer Piping Systems, Georg Fischer Harvel LLC, 300 Kuebler Road, Easton, PA 18040, USA, Tel: 610-252-7355, Website: www.GFPiping.com - retrieved 18 March 2015, original source: http://www.envirokinguv.com/design-installation/set-cure-times The company has offices in the U.S. in Connecticut, Hawaii, Illinois, Indiana, Iowa, Kentucky, Maine, Massachusetts, Michigan, Minnesota, Missouri, Nebraska, New Hampshire, North Dakota, Ohio, Rhode Island, South Dakota, Vermont, Wisconsin, Wyoming, and in Canada in Ontario, Quebec, Alberta, Manitoba, Saskatchewan, New Brunswick, British Columbia. Canada Tel: +1-905-670-8005, Email: Kuno Lischer, President, kuno.lischer@georgfischer.com
Oatey, "Oatey® Solvent Cements Set Up / Curing Times", Oatey®, 4700 W. 160th St. I Cleveland, OH 44135
800.321.9532 I Fax: 800.321.9535
www.oatey.com, retrieved 18 March 2015, original source http://www.homedepot.com/ catalog/pdfImages/d2/d25ece3c-3e81-4223-9270-c18977273030.pdf
Vinidex, "Technical Note VX-TN-10D, Do's and Don't of Solvent Cementing Pressure Pipes", retrieved 18 March 2015, original source: http://www.vinidex.com.au/technote-parent-page/dos-and-donts-of-solvent-cementing-pressure-pipes/
Weld-On Solvent Cements Set and Cure Times, retrieved 18 March 2015, original source: http://www.weldon.com/pdf/weldon/WeldOn_SetCure_Timetable_Jul09.pdf
Eric Galow, Galow Homes, Lagrangeville, NY. Mr. Galow can be reached by email: ericgalow@gmail.com or by telephone: 914-474-6613. Mr. Galow specializes in residential construction including both new homes and repairs, renovations, and additions.
Mark Cramer Inspection Services Mark Cramer, Tampa Florida, Mr. Cramer is a past president of ASHI, the American Society of Home Inspectors and is a Florida home inspector and home inspection educator. Mr. Cramer serves on the ASHI Home Inspection Standards. Contact Mark Cramer at: 727-595-4211 mark@BestTampaInspector.com
John Cranor [Website: /www.house-whisperer.com ] is an ASHI member and a home inspector (The House Whisperer) is located in Glen Allen, VA 23060. He is also a contributor to InspectApedia.com in several technical areas such as plumbing and appliances (dryer vents). Contact Mr. Cranor at 804-873-8534 or by Email: johncranor@verizon.net
[3] PB (polybutylene with mechanical fittings) Piping leaks: especially in mobile homes and in the U.S. South, for example trailers and double-wides throughout Florida that were piped with this material - per M Cramer. See "Polybutylene Piping: Time Bomb?" Daniel Friedman, Journal of Light Construction, August 1996 [Technical Q&A].
[4] ABS Plastic Pipe: "All Black -hit," defective black ABS plastic waste pipe manufactured in the mid 1980's failed by cracking. Additional information: www.abspipes.com
[5] Polybutylene Plumbing (plastic pipes): gray plastic water supply piping cracked, leaked, and resulted in a class action and settlement.
Eric Galow, Galow Homes, Lagrangeville, NY. Mr. Galow can be reached by email: ericgalow@gmail.com or by telephone: 914-474-6613. Mr. Galow specializes in residential construction including both new homes and repairs, renovations, and additions.
[7] PB Technology Center (information about PB Pipes) Tel: 800-338-7732, also see the 1990 PB Pipe recommendations published by the Polybutylene Product Line Committee of the Plastic Pipe and Fittings Association.
Polybutylene Plumbing Failures: Spencer Class settlement, Web: spencerclass.com, 10% of replacement cost/damages, only for acetal (plastic)fittings
[11] plumbing911.com/poly/ Polybutylene Plumbing Failures , Lots of Info about, but slow-loading busy site - now dead 2024/01/24
[12] Zurn Manufacturing, Web: zurn.com , Zurn Pex, Inc., Highway 11 East, Commerce, TX 75428, Tel: (903) 886-2580
provides information about installing and using PEX piping including Type b PEX through their website. Quoting from the company's website Zurn was founded in 1900 in Erie, PA. It originally manufactured a patented backwater valve, and it now manufactures and distributes one of the largest plumbing products packages in the world! Zurn includes: the Specification Drainage Operation, AquaFlush flush valves, AquaSense sensor-operated plumbing products, AquaSpec commercial faucets, Wilkins, Zurn Light Commercial, Flo-Thru, the Chemical Drainage Systems, Zurn PEX Plumbing Systems and Zurn Radiant Heat.
[13] Zurn PEX PLUMBING DESIGN AND APPLICATION GUIDE [PDF] - web search 2023/04/06 & 12/23/2010, original source zurn.com/operations/pexrh/pdfs/installation/PEXDesApplGuide.pdf
[14] Zurn Pex Plumbing
Products Liability Litigation, United States Court of Appeals
FOR THE EIGHTH CIRCUIT, No. 10-2267, Filed 6 July 2011, Quoting: Minnesota homeowners brought this action1 against Zurn Pex, Inc. and Zurn
Industries, Inc (Zurn) alleging that brass fittings used in the company's cross linked
polyethylene (PEX) plumbing systems are inherently defective. In pretrial motions
the homeowners sought class certification for their consumer protection, warranty, and
negligence claims, and Zurn moved to strike the testimony of two of the homeowners’
experts. After denying Zurn's motion to strike the expert testimony, the district court2
granted the homeowner requests for class certification for their warranty and
negligence claims, but denied it for their consumer protection claims. Zurn appeals
from the district court's certification order. We affirm. Web search 4/12/12, original source: www.ca8.uscourts.gov/opndir/11/07/102267P.pdf
[15] Uponor, Inc., F1807 Plumbing Court File No. - United States District Court, District of Minnesota, In Re: Uponor, Inc., F1807 Plumbing Court File No. 11-MD-2247 ADM/JJK
Fittings Products Liability Litigation, " Order Granting Motion to Certify Class for Settlement Purposes and for Preliminary Approval of Class Action Settlement and Form and Dissemination of Notice to the Class" Quoting: The Motion for Preliminary Approval of Class Action Settlement was heard on January 12, 2012. After review of pleadings and briefing, and having heard the arguments of counsel for good cause shown, it is hereby ORDERED that: (1) the Motion for Preliminary Approval of Nationwide Class Action Settlement Agreement; (2) preliminary and conditional certification of a settlement class; (3) approval of the form and content of Notice and Settlement; (4) an injunction and stay of all claims and actions against the RTI Defendants Web search 4/12/12, original source: http://www.mnd.uscourts.gov/MDL-Uponor/
[16] Bonnie Ransom Stern & Gustavo Lagos, "Are There Health Risks from the Migration of Chemical Substances from Plastic Pipes into Drinking Water? A Review", Human and Ecological Risk Assessment: An International Journal
Volume 14, Issue 4, 2008, Abstract: Plastic pipes used to convey hot and cold drinking water are synthetic polymers containing numerous additives that enhance durability, impact strength, and toughness, and resist material degradation. Although some research studies have been conducted to evaluate the type and levels of chemical substances migrating from polymeric materials into drinking water, the potential adverse health effects associated with these compounds in potable water have not been described. This review evaluates the literature on the occurrence of regulated and unregulated substances in drinking water related to the use of plastic pipes, characterizes potential health hazards, and describes uncertainties associated with human health and exposure in need of further research. Of particular public health concern is the potential for sensitive populations to be exposed to short-term elevations in leachates during critical periods, and for co-occurring leachates targeting the same organ(s) and/or sharing a common mode of toxic action to have additive or synergistic effects. Contaminants are measured in the distribution system, not at the tap where human exposure actually occurs. For increased health protection, it is important to identify compounds that migrate from plastic pipes into drinking water and to better quantify human exposures and health hazards to these substances and their degradates.
[17] Andrew J. Whelton, Andrea M. Dietrich, Daniel L. Gallagher, "Chapter 6 Impact of Chlorinated Water Exposure on Chemical Diffusivity and Solubility,
Surface and Bulk Properties of HDPE and PEX Potable Water Pipe", in Advancing Potable Water Infrastructure through an Improved Understanding of Polymer
Pipe Oxidation, Polymer–Contaminant Interactions, and Consumer Perception of Taste, Andrew James Whelton
Dissertation submitted to the Faculty of the
Virginia Polytechnic Institute and State University
In partial fulfillment of the requirements for the degree of
DOCTOR OF PHILOSOPHY
In
Civil Engineering
Andrea M. Dietrich, Chair
Daniel L. Gallagher
Marc A. Edwards
Brian J. Love
James M. Tanko, April 2, 2009
Blacksburg, Virginia. Abstract: While more than 100 years of research has focused on removing acute and chronic health threats from water, substantially less study has focused on potable water infrastructure and water quality deterioration, monitoring technologies, and relationships between water taste and consumer health. These knowledge–gaps have left infrastructure users, owners, regulators, and public health professionals largely unaware of how premise and buried polymer water pipes deteriorate and sorb/ desorb organic contaminants during normal operations and following water contamination events. These knowledge–gaps also prevent infrastructure managers from producing drinking water that optimizes mineral content for both water taste and health benefits, and employing a monitoring tool capable of immediately detecting water contamination or equipment failures. Research was conducted to address these challenges using analytical chemistry, environmental engineering, food science, polymer chemistry, public health, and material science principles. This work was enhanced by collaborations with sixteen American water utilities and the National Institute for Standards and Technology. These efforts were funded by the National Science Foundation, American Water Works Association, and the Water Research Foundation. Research results are unique and provide important scientific contributions to the public health, potable water, and material science industries. Particular achievements include the: (1) Evaluation of linkages between minerals, water palatability, and health useful for water production and public health decisions; (2) Creation of a novel infrastructure and water quality surveillance tool that has begun water utility implementation in the USA; (3) Development of an accelerated chlorinated water aging method with stable water pH, free chlorine, and alkalinity concentration that enables interpretation of polymer pipe surface and bulk characteristic changes; (4) Discovery that polar compounds are 2–193% more soluble in PEX than HDPE water pipes; (5) Finding that several polymer and contaminant properties can be used to predict contaminant diffusivity and solubility during sorption and desorption in new, lab aged, and water utility PE pipes; and the (6) Discovery that chlorinated water exposure of HDPE and PEX pipes increases polar contaminant diffusivity during sorption by 50–162% and decreases diffusivity during desorption as much as 211%. Outcomes of this work have domestic and global significance, and if engaged, can greatly improve public health protection, potable water infrastructure operations, water quality, sustainability, and regulation.
[18] Chemax, "Cross-Linked Polyethylene Tubing and Water Contamination", retrieved 2/17/2013, original source: http://www.chemaxx.com/polytube1.htm [copy on file as [Water Contamination chemical investigation.pdf]
[19] Ingun Skjevrak, Anne Due, Karl Olav Gjerstad, Hallgeir Herikstad "Volatile organic components migrating from plastic pipes (HDPE, PEX and PVC) into drinking water", Water Research Volume 37, Issue 8, April 2003, Pages 1912–1920 Abstract:
High-density polyethylene pipes (HDPE), crossbonded polyethylene pipes (PEX) and polyvinyl chloride (PVC) pipes for drinking water were tested with respect to migration of volatile organic components (VOC) to water. The odour of water in contact with plastic pipes was assessed according to the quantitative threshold odour number (TON) concept. A major migrating component from HDPE pipes was 2,4-di-tert-butyl-phenol (2,4-DTBP) which is a known degradation product from antioxidants such as Irgafos 168®. In addition, a range of esters, aldehydes, ketones, aromatic hydrocarbons and terpenoids were identified as migration products from HDPE pipes. Water in contact with HDPE pipes was assessed with respect to TON, and values ⩾4 were determined for five out of seven brands of HDPE pipes. The total amount of VOC released to water during three successive test periods were fairly constant for the HDPE pipes. Corresponding migration tests carried out for PEX pipes showed that VOC migrated in significant amounts into the test water, and TON ⩾5 of the test water were observed in all tests. Several of the migrated VOC were not identified. Oxygenates predominated the identified VOC in the test water from PEX pipes. Migration tests of PVC pipes revealed few volatile migrants in the test samples and no significant odour of the test water.
[20] Andrew J. Whelton, Ph.D., M.ASCE; Andrea M. Dietrich, Ph.D., Aff.ASCE; and Daniel L. Gallagher, Ph.D., P.E., M.ASCE, ”Contaminant Diffusion, Solubility, and Material Property Differences between HDPE and PEX Potable Water Pipes.” J. Environ. Eng., 136(2), 227–237.
doi: 10.1061/(ASCE)EE.1943-7870.0000147 Abstract: the objectives of this work were to identify differences between the composition, bulk properties, contaminant diffusivity and solubility for new high-density polyethylene (HDPE) pipe and crosslinked polyethylene (PEX) pipe, as well as determine which contaminant and polymer properties are useful for predicting contaminant fate in water pipe. Variations in PE pipe density (0.9371–0.9547 g/cm3) , crystallinity (69–72%), crosslinking (60 and 76%), and oxidative induction time (33 to >295 min .) were detected. While numerically these differences seem minor, results show that slight material differences have a notable effect on contaminant diffusivity and solubility. Nonpolar contaminant diffusivity and solubility were best predicted by bulk density. Polar contaminants were more soluble and diffused faster through PEX than HDPE pipes because PEX pipes contained a greater amount of oxygen. For all materials, dipole moment and Log Kow were good predictors of contaminant fate and molecular volume was only useful for predicting diffusivity and solubility values for haloalkane and nonpolar aromatic contaminants.
[21] Jia Tang, Daniel L. Gallagher, and Andrea M. Dietrich. (2013) Predicting Permeation of Organic Contaminants into Polyethylenes. Journal of Environmental Engineering 139:2, 205-212
Online publication date: 1-Feb-2013. Abstract: A model was developed and validated for predicting solubility and diffusion coefficients for contaminants permeating polyethylene (PE) materials used for water pipes and geomembranes. Model development was based on diffusivity and solubility of 13 contaminants and six PE materials that were new and/or aged in chlorinated water. Physical and chemical properties of the contaminants and PEs were included as variables in the model. Tree regression was used to select variables, and multiple linear regression was used to develop predictive equations for contaminant diffusivity and solubility in PE. Organic contaminant properties, especially dipole moment and octanol-water partition coefficient, had greater predictive capability than PE properties. Coefficients of determination (R2)>0.8 were obtained for the multiple linear regressions. Model coefficients changed slightly between new PE materials and chlorine-aged PE, but these changes were not statistically significant. Good agreement was demonstrated between model predictions and measured data from an independent data set. These results provide guidance for material selection for both water pipes and geomembranes and assessing contamination potential.
[22] Andrew J. Whelton, Andrea M. Dietrich, and Daniel L. Gallagher. (2011) Impact of Chlorinated Water Exposure on Contaminant Transport and Surface and Bulk Properties of High-Density Polyethylene and Cross-Linked Polyethylene Potable Water Pipes. Journal of Environmental Engineering 137:7, 559-568
Online publication date: 1-Jul-2011. Abstract: The aim of this work was to determine if the aging of polyethylene (HDPE, PEX-A and PEX-B) water pipes by exposure to chlorinated water altered polar and nonpolar contaminant diffusivity and solubility by analyzing new, laboratory-aged, and exhumed water-distribution system polyethylene (PE) pipes. After 141 days of aging in pH 6.5 water with 45 mg/L free chlorine, the surface chemistry and bulk properties of PEX-A pipe were unaffected. Carbonyl bonds (σ=1,713 cm−1) were detected on the surfaces of HDPE and PEX-B pipe, and these oxygenated surfaces became more hydrophilic, resulting in statistically significant increases in diffusion rates. All 10 contaminant and four pipe material combinations had diffusivity increases on average of 50% for polar contaminants and 5% for nonpolar contaminants. Contaminant solubility was slightly increased for aged PEX-A and slightly decreased for PEX-B pipes. Toluene and trichloromethane diffusivity and solubility values for 7- to 25-year-old buried water utility pipes were similar to values for new and laboratory-aged HDPE-based materials. Because chlorinated water exposure alters how polar contaminants interact with aged PE pipes, results of this work should be considered in future health risk assessments, water quality modeling, pipe performance, and service-life considerations.
[23] ANDREW J. WHELTON & TINH NGUYEN, "Contaminant Migration from Polymeric Pipes used in Buried Potable Water Distribution Systems: A Review", Critical Reviews in Environmental Science and Technology, February 2012 posted online, Abstract: Polymeric pipes are increasingly being installed in water distribution systems because of their many advantages. Contaminant migration from polymer pipes into drinking water is a growing concern in the United States and environmental engineers are evaluating the role of these materials on water quality, system operation, and regulatory compliance. To aid these efforts and serve as a source of background information, this paper critically reviews available literature on polymeric potable water pipes in use, known contaminants released from in–service and new piping, their perceived sources, and outlines future challenges in the U.S. and abroad.
[24] Andrew James Whelton, "Advancing Potable Water Infrastructure through an Improved Understanding of Polymer
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In partial fulfillment of the requirements for the degree of
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Cheating on water tests: Testing Water for Real Estate Transactions - make sure your water test is valid
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