InspectAPedia®   -   Search InspectApedia

Ceramic floor tile - asbestos containing © D Friedman at InspectApedia.com Asbestos & Lead Content in Ceramic Floor Tile or Ceramic Wall Tile?

Do or did ceramic or porcelain wall or floor tiles contain asbestos or lead?

Do or did tile grout, tile bedding compounds, thin-set mortars, or tile mastic used with ceramic tiles contain asbestos or lead?

We explain the ingredients in ceramic floor tiles, cite authoritative research on the presence or absence of asbestos in these ceramic tile, or its absence, and we point to sources of confusion about the question of which ceramic products (tiles, pottery, filters) contain or ever contained asbestos as a filler or as a fiber strengthener.

We include research citations indicating various hazards in the production of some tile products.

We report on an international survey of certified asbestos testing laboratories who were asked for their experience in receiving ceramic tile samples or mortar/grout samples and testing them for asbestos content.

InspectAPedia tolerates no conflicts of interest. We have no relationship with advertisers, products, or services discussed at this website.

- Daniel Friedman, Publisher/Editor/Author - See WHO ARE WE?

Does Ceramic Floor Tile or Ceramic Wall Tile Contain Asbestos?

Ceramic floor tile - asbestos containing © D Friedman at InspectApedia.com

Is asbestos found non-resilient flooring such as ceramic floor tiles?

Our page top photo illustrates a fragment-section of old ceramic floor tile. At left we show a side-view or cross-section of how this old ceramic floor tile was installed by bedding it directly into concrete. We would not expect to find evidence of asbestos in this tile installation.

[Click to enlarge any image]

This example was found in a pile of demolition debris left at a building renovation site. The tile was set into and well bonded to concrete, and was removed under wet conditions.

The short answer for now appears to be "yes and no" depending on the tile and tile grout age and source, as follows:

Antique ceramic tile, Barcelona, Spain © D Friedman at InspectApedia.com

Details, including authoritative citations and an ongoing survey of the results of tile testing at asbestos testing labs in the U.S., Canada, Japan, Korea, the U. K. and other locales are provided below.

OPINION: researching this question we find that the dominant opinion among experts and amateurs is that ceramic tiles are made of clay subjected to high temperatures and finished with a hard glazed surface. Not asbestos.

If there are some ceramic tiles whose clay source included asbestos or to which asbestos was added [a topic of ongoing research that we report and update below] the tiles are nevertheless a non-friable material that would not normally be a hazardous source of asbestos in buildings.

Non-friable materials are hard and do not easily release particles into the indoor environment.

Watch out: grinding, tile-saw cutting, sanding or similar activities performed on ceramic tiles of any composition could produce fine dust and debris that should be controlled and treated as a respiratory hazard, asbestos-containing or not.

See ASBESTOS REMOVAL, WETTING GUIDELINES

Do Ceramic Floor or Wall Tiles Contain Dangerous Levels of Asbestos or Not ? - research question status

Antique ceramic flooring in Barcelona Spain © D Friedman at InspectApedia.com

Deliberate Inclusion of Asbestos as an Add-in to Ceramic Tiles?

Asbestos could have been included in some ceramic floor tile formulas into the 1970's as a filler or in fiber form as a strengthener.

At least one asbestos testing lab director reports that asbestos is found in ceramic tiles made in some parts of the world such as the Mediterranean area and in unglazed terrazzo (non-ceramic) tiles.[44]

Below at CHINESE CERAMIC TILE ASBESTOS we discuss reports of asbestos in some recent Chinese ceramic tile and flooring products.

Don't Confuse Asphalt-based or Vinyl-based Asbestos-containing Floor Tiles with Ceramic Tile Products

In our flooring photograph at left, the floor and stair tiles may be vinyl-asphalt or vinyl-asbestos floor tiles but they are not a ceramic product. For information about asbestos-containing vinyl or asphalt-based floor tiles,

see ASBESTOS FLOORING IDENTIFICATION.

Certainly as we see in Rosato [23], the asbestos industry was constantly looking for uses of asbestos mining waste products that included granular asbestos dust and short asbestos fibers.

Although we cite field and lab reports and research in this article, we have not yet located an authoritative reference source (text, journal article, government document) that documents the deliberate or accidental inclusion of asbestos material added to modern (20th century and later) ceramic floor or wall tiles made in North America. Please contact us if you have such information.

In contrast, it is certain asbestos was used in those forms in vinyl-asbestos flooring (a different material from ceramic tiles). And as we document below, asbestos was used in mixture with ceramic fibers (for certain products such as filters) and in ancient pottery applications.

Our photo above illustrates a floor tile installation in Barcelona, Spain. These floor tiles are estimated at more than 50 years old.

Do new ceramic tiles from China contain asbestos?

The ceramic tile that we purchased for our bathroom wall was made in China. What are the chances that it would contain asbestos? - question from Anon by private email 2017/03/24

A quick search for "Asbestos in Tile from China" intended to collect results on asbestos in ceramic tile made in China found these interesting and suggestive results, giving a definite possibility that your Chinese-made ceramic tiles could contain asbestos.

The most strongly-worded material comes from news reports, after which I cite some more-scholarly research on asbestos in Chinese ceramic tiles used on walls and floors.

Ceramic tile is not friable - if your particular tile contains asbestos, the measurable asbestos risk would come with cutting, grinding, chopping, demolishing the building material to create an asbestos-containing dust hazard.

What is the Composition of Ceramic Tiles?

Is there Accidental Inclusion of Asbestos in Clays Mined for Use in Producing Traditional Ceramic Tiles?

The term "clay" refers to both a particle size (smaller than 2-4mm) and a type of rock or mineral comprised of fine-grained sheet silicates.[48] The fine-grained clays used to manufacture ceramic tiles include basically compounds of silica, alumina, and varying amounts of metallic oxides and other impurities. [32]

Ceramic tiles are made from natural clay [such as Cretaceous clays [30] (not asbestos)] or porcelain, and are glazed or un-glazed.

Typical ceramic tile composition (in more detail) includes 33% refractory clay, 20% quartz, 45% sodium feldspar. Other sources list common tile ingredients including aluminum oxide, zirconium oxide, and quartz (silicon dioxide). Other ceramics have more complex formulas.

Ceramic tiles

are made of clay (predominantly feldspar), water, and some mineral additives, processed with high heat to solidify the product and whose top or exposed surface is sealed with a glaze.

Porcelain tiles

are a harder ceramic tile made of kaolin mixed with china stone, or in other sources, by using ground sand. Porcelain is heated to a higher temperature than other ceramics (more than 2000 degF) and is more dense than ceramic materials made of clay.

Many other materials have been included in clays used in making various ceramic products since the Stone Age (pottery) and continue to be added to give special properties or colors to modern ceramic tiles, including perlite, fly ash, granite stone grinding and cutting waste, etc. Indeed expert sources date the oldest known ceramics date to 27,000 BCE.

The oldest known ceramics made by humans are figurines found in the former Czechoslovakia that are thought to date from around 27,000 B.C.E.

It was determined that the figurines were made by mixing clay with bone, animal fat, earth, and bone ash (the ash that results when animal bones are heated to a high temperature), molding the mixture into a desired shape, and heating it in a domed pit.

The manufacture of functional objects such as pots, dishes, and storage vessels, was developed in ancient Greece and Egypt during the period 9000 to 6000 B.C.E. [33]

We have not found a citation that includes asbestos among these. Contact us if you have related information.

List of Authoritative sources reporting the use of [or absence of] asbestos in any form of ceramic floor tiles

Do ceramic tiles risk releasing harmful particles into indoor air?

Ceramic floor or wall tiles of any formula, if in good condition have a low, most likely negligible risk of releasing harmful particles or fibers into indoor air. And a ceramic tile that comes loose intact or with a single break is also unlikely to release a measurable amount of dust or particulates into the building.

Watch out: Phillip A. Peterson Vice President Fibertec Industrial Hygiene Services, Inc.[49] advises that Although the tile themselves are unlikely to contain asbestos, the grout and bedding may well contain asbestos and the demolition of the tile will likely create an exposure hazard when the grout and/or bedding are disturbed.

Ceramic floor tiles that are being demolished, ground, sanded, or cut with a tile saw, if they are old enough to have been installed when asbestos was in common use in grout, tile bedding, or (in newer homes) thin set or tile mastic, could be hazardous and should be handled appropriately.

If you are considering demolition of old ceramic floor tiles or similar materials, or are using a sander, grinder or tile saw on such materials, there could indeed be an asbestos hazard and you should follow appropriate handling, dust control, personal protection, and cleanup procedures.

If you have a segment of floor tile (or any material) tested for asbestos the test should be performed by a certified asbestos testing laboratory.

In Any Case, Better to Leave Asbestos-Containing Floor Tiles In Place

As with known or suspected asbestos-containing floor tiles (such as asphalt or vinyl-asphalt asbestos floor tiles), when it's feasible expert sources recommend leaving the original floor tile material in place and covering it over with new flooring.

Leaving asbestos-suspect flooring in place, even if you need to level the floor before it is covered with new material, is not only less costly than a professional asbestos abatement project, it also is likely to be the course with the lowest risk of asbestos dust or fiber release and contamination in the building. According to the US EPA {discussing asbestos abatement in schools] :

... In addition, abatement activities may create more of a hazard than would normally exist if the ACM were simply protected and maintained in good condition as is the case for ceramic floor tiles. ...[3]

Similar sources indicate that simple deconstruction of a building with appropriately careful disassembly of its parts may not require asbestos abatement. [4]

Details about covering-over asbestos-containing floor tiles or other ACM flooring such as resilient sheet flooring are

at ASBESTOS FLOORING HAZARD REDUCTION

Special thank-you to reader A.H. who suggested clarification about the risk that ceramic wall tiles or ceramic floor tiles might contain asbestos. - Ed.

Contaminants & Health Hazards Ceramic Tile & of Other Ceramics: Clays, Pottery, Art Studios

For potential health hazards associated with exposure to artists materials for those working with ceramics, such as clays, glazing compounds, and pigments, see

our "ARTS & CRAFTS MATERIAL HAZARDS & TOXICITY entry included

at ENVIRONMENTAL HAZARDS - INSPECT, TEST, REMEDY and references at the end of this article. [51][52][53]

Also, as ingredients used in the manufacture of some ceramic tiles or in tile glazing may contain surprising contaminants of a wide variety, including heavy metals, lead, possibly arsenic, and radioactive materials, see

Survey Results: Accredited Laboratories Asbestos Fiber Analysis in Ceramic Tiles

Beginning in March 2012, and using the U.S. NIST directory of accredited laboratories certified for asbestos fiber analysis, [42] we polled at least one laboratory in each U.S. state, Puerto Rico, two Canadian Provinces, and laboratories in Japan and Korea, asking each if their laboratory had ever received ceramic tiles for asbestos testing and whether or not their lab had ever detected asbestos in ceramic tiles used on walls, floors, or other building services. Results are included below.

We asked:

"Can you tell us if your laboratory has ever received samples of ceramic wall or floor tile to test for asbestos, tell us if you have encountered asbestos in ceramic tiles used on walls or floors, and/or can you provide a reference to a paper, study, book, or expert who can tell us whether or not asbestos in any form was used in the production of ceramic wall tile or floor tile, or in terra-cotta or similar tile products."

and we invited technical review of the article found on this web page.

Table of Asbestos Test Labs Reporting Finding Asbestos in Ceramic Materials or Tiles

Survey
Respondents to Date

(n=55) (r=6)

Estimated
Avg.
Exper-
ience
Tile
Testing3
(R = 5 - 40)
Asbestos Detected in Ceramic Floor/Wall
Tiles
Estimated
Total
Tile Samples
Tested3
Estimated
Avg.
Exper-
ience
Years
Grout
Testing3
(R = 4 - 40)
Asbestos Detected in
Tile Grout,
Bedding
Mastic
Estimated 3
Total
Grout Samples Tested 3
Date: 4/23/12(1)
           
6
15

Never - 84%

Common - 16% (2)

540 10

Never - 25 %
Rare - 50%
Common - 25%

15004

Notes to the table above:

(1) Survey initiated 3/8/2012

(2) Asbestos reported as extensive in ceramic tiles made out of North America, particularly in the Mediterranean area[44]

(3) Our calculated estimate of total number of actual lab samples processed by laboratories responding to the survey. Based on correspondence, e.g. P. P. to D.F. 3/14/12[49] estimated less than 150" tile samples over 20 years of ceramic tile, & 200 grout & bedding samples over 8 years of testing.

We estimated 6 tile samples per year or 25 grout samples per year per responding lab, and and multiplied that by known or estimated number of years of lab testing of tiles or grout. [E.g. 200 samples/8 yrs = 25 grout samples/year. 25 x 6(labs) x 10 yrs) =1500]

(4) In every case the asbestos mineral has been chrysotile asbestos and the concentration of asbestos has exceeded 2 percent (making them asbestos containing materials by definition). [49]

Watch out: while asbestos may be absent from your ceramic tile found on walls or floors, it may be present in joint compound used on drywall behind the tile or in some tile adhesive mastics. Also some ceramic tiles may contain lead.

...




ADVERTISEMENT





Reader Comments, Questions & Answers About The Article Above

Below you will find questions and answers previously posted on this page at its page bottom reader comment box.

Reader Q&A - also see RECOMMENDED ARTICLES & FAQs

Will I release dangerous asbestos if I clean these black and white ceramic floor tiles from a 1948 home in Georgia?

Black and white ceramic bath tile floor in a 1948 Georgia home - does it contain dangerous asbestos, and can we clean it? (C) InspectApedia.com B.C. 2018/05/06 Brittney said:

I’m wondering if you are able tell/may know if these floors contain asbestos just by looking at them?

My husband and I just purchased this house built in 1948 in Georgia. And I hadn’t thought much about asbestos in floors until finding this website and now I’m concerned. (See attached pic).

Do you think scrubbing the floors/grout should be safe ?

This question and reply were posted originally

at ASBESTOS FLOORING IDENTIFICATION

Reply:

It appears to me you're asking about a ceramic tile floor.

If That's the case, even if the style contained asbestos, which would be quite uncommon, the asbestos risk is beneath the limits of detection unless you're grinding chopping or sawing the material.

Cleaning the floor in your photos is not going to produce a measurable hazard even if there was asbestos in the tile or its grout - a situation that would be quite uncommon - as the materials are very hard and not at all friable.

Typically we need to use a liquid cleaner that includes mild bleaching agent to whiten the floor tile grout.

Reader follow-up: I don't want the Chinese ceramic tile in my home: plans to remove Chinese Ceramic Tile

Well the flooring says made in PRC.....that means People's Republic of China.

Ii realize where the "measurable risk" comes from but since my now deceased husband died of mesothelioma, from supposed MINIMAL exposure to asbestos I don't want ANYTHING containing asbestos in my home.

Unfortunately the ceramic tile has already been installed and that involved lots of cutting. The flooring has not so I will be returning it. I have contacted the company from which I purchased the material but have not yet heard back from them.

Reply: minimize the risk of installed Chinese asbestos-suspect ceramic tile

I don't blame you for taking these things seriously, and I'm cautious too about products from China - there have been enough disasters already.

What I meant by measurable risk is that installed ceramic tile is not going to release asbestos at detectable levels in a building unless it's disturbed.

While it's a different product (flooring) the US EPA advice on minimizing asbestos hazards in the home emphasizes that unless the asbestos-containing but non-friable material is damaged or being disturbed, the lowest risk to occupants is to leave it alone, or perhaps cover it over.

Removing it will expose you and the building and its occupants to a much greater risk, even if you hired a professional remediator who used negative air, containment, etc. (you're looking also at a very big cost).

OPINION: My advice is to leave the tile in place, or if it's going to make you worry - which is itself bad for us - you could consider laminating over the existing tile with a second layer of new material in which you have confidence.

That may at most require some adjustments at the tub/shower controls to bring them forward.

Question: does this [ceramic] floor tile contain asbestos?

Ceramic floor tile  asbestos question (C) InspectApedia EP

My husband & I are planning on replacing the floor tile in our entryway. I'm trying to research to see if it could contain asbestos as we have two young children. Our home was built in 1965 in a Pittsburgh suburb.

Could you take a look at this picture and let me know what you think? Thank you! - anonymous by private email, 2016/07/15

Reply:

From your photo this looks like ceramic floor tile. If it is a modern, U.S.-made product it probably does not contain asbestos. However some mastic adhesives did contain asbestos so care in removing that material would be appropriate.

See ASBESTOS-CONTAINING ADHESIVES

If you cannot remove the flooring without making a dusty mess, it may be worth having a sample of tile and more-likely the adhesive mastic tested.

See ASBESTOS TESTING LAB LIST

If you do decide to have the materials tested let us know the result as that may help other readers.

On 2023-08-29 by Brian - Asbestos likely in 1960's ceramic tile in a Florida home?

My house was built in 1964 in Florida. I have 6x6 tiles that I believe are ceramic. What are the chances they contain asbestos? (I know I have asbestos in the popcorn ceiling already).

6x6 ceramic tile (C) InspectApedia.com Brian

On 2023-08-29 by InspectApedia DF (mod)

@Brian,

It is unlikely if the tile was produced in the US. Although you may find asbestos in some tile grouts and thinset tile mastics.

Also keep in mind that even if the tiles did contain asbestos, if in good condition, they are nevertheless a non-friable material that would not normally be a hazardous source of asbestos in buildings

Please read more above on this page.

On 2023-09-01 by Brian

@InspectApedia DF, so it should be safe to remove the tile, grout and thin set so long as we are careful not to damage it too much?

Thank you.

On 2023-09-01 by InspectApedia Publisher

@Brian,

We don't know if your ceramic tile, grout, and adhesive mastic contain asbestos or not. Even if not, silica dust is hazardous, so if you're chopping grinding sawing the hazard is increased.

Beyond that, as I can't see the job and have no specifics, any answer is - sorry - just too speculative to be accurate.

 

On 2022-01-19 by Ryan - Boss didn't check ceramic tiles or mastic fdor asbestos

Just having to reno a bathroom. Boss didn't check tiles and mastic for asbestos. Nor did he check the multiple layers of vinyl tilea/sheet vinyl.

White Ceramic Tile (C) Inspectapedia Ryan

These tiles look old enough to be a concern for at least grout/mastic exposure.

They have been painted white.. which also makes me wonder if someone else knew they contain asbestos. Thoughts?

 

On 2021-11-16 by Asbestos grout in kitchen...?, is it safe to live-in or even visit these apartments or condos?

Whats the percentage/chance that the grout would contain asbestos in kitchen counter and bahtroom please in California? High chance?

Now I feel worried to use the counter as mugs and pots are coming with contact with the kitchen tiles/grout every day.

Is it even safe to live in these possible asbestos houses? And is the garage and window safe in your opinion?

And when they cutting walls on that neighbours house without protections and just throwing in a truck without putting in bags, is that something to worry about, or is that normal procedure and the possible asbestos would not really affect house next to it or air while walking around the house.

Wondering also how safe it is to visit them. Thank you! - Ryan

...

On 2021-11-17 by Inspectapedia Com Moderator

@Asbestos grout in kitchen counter/shower, window, garage?,

The probability of the Airborne asbestos at detectable levels from bathroom or other undisturbed, intact ceramic tile and tile grout is quite low but of course not zero as you can read in the article above on this page.

@ Asbestos grout in kitchen...?,

On 2021-11-17 by Asbestos grout in kitchen...?

@Inspectapedia Com Moderator, i understood that there is now low asbestos in the kitchen since not zero, what is not the worst but also not the best and safest, but was also wondering if most of the grout was with asbestos, or only little percentage, if someone would know that. Thank you.

On 2021-11-17 by Inspectapedia Com Moderator

@ Asbestos grout in kitchen...?,

Not without more specific details or actual testing

How did we get from low

On 2022-01-19 by Inspectapedia Com Moderator

@Ryan,

Keep in mind that ceramic tile is anything BUT friable: it's hard as the dickens. You can't make hazardous dust from such material unless you're doing a demolition. Any mastic would have been behind the tile.

probability high worry?

...

Continue reading  at at FLOOR, CERAMIC TILE or select a topic from the closely-related articles below, or see the complete ARTICLE INDEX.

Or see CERAMIC TILE, ASBESTOS / LEAD FAQs - questions & answers posted originally at the end of this page

Or see these

Recommended Articles

Suggested citation for this web page

CERAMIC TILE, ASBESTOS / LEAD? at InspectApedia.com - online encyclopedia of building & environmental inspection, testing, diagnosis, repair, & problem prevention advice.


Or see this

INDEX to RELATED ARTICLES: ARTICLE INDEX to ASBESTOS HAZARDS

Or use the SEARCH BOX found below to Ask a Question or Search InspectApedia

Ask a Question or Search InspectApedia

Try the search box just below, or if you prefer, post a question or comment in the Comments box below and we will respond promptly.

Search the InspectApedia website

Note: appearance of your Comment below may be delayed: if your comment contains an image, photograph, web link, or text that looks to the software as if it might be a web link, your posting will appear after it has been approved by a moderator. Apologies for the delay.

Only one image can be added per comment but you can post as many comments, and therefore images, as you like.
You will not receive a notification
when a response to your question has been posted.
Please bookmark this page to make it easy for you to check back for our response.
Our Comment Box is provided by Countable Web Productions countable.ca

Comment Form is loading comments...

Citations & References

In addition to any citations in the article above, a full list is available on request.

  • [1] EPA, U.S. Environmental Protection Agency, Asbestos in Your Home, web search 08/31/2011, original source: www.epa.gov/asbestos/pubs/ashome.html
  • [2] EPA Guidance for Controlling Asbestos-Containing Materials in buildings, NIAST, National Institute on Abatement Sciences & Technology, [republishing EPA public documents] 1985 ed., Exposure Evaluation Division, Office of Toxic Substances, Office of Pesticides and Toxic Substances, U.S. Environmental Protection Agency, Washington,D.C. 20460
  • [3] EPA: "Asbestos Management", U.S. Environmental Protection Agency, Region 7, original author: Todd H. Dresser, Environmental Engineer, (formerly of), Burlington Board of Health, 29 Center Street, Burlington, MA 01803, web search 3/4/2012 original source: epa.gov/region07/education_resources/teachers/ehsstudy/ehs2.htm, [copy on file as: /hazmat/Asbestos Management _ Region 7 _ US EPA.pdf ]
  • [4] US EPA, DECONSTRUCTION - BUILDING DISASSEMBLY AND MATERIAL SALVAGE - THE RIVERDALE CASE STUDY [PDF] U.S. EPA, web search 3/4/12, original source: epa.gov/wastes/conserve/rrr/imr/cdm/pubs/river.pdf, [copy on file as: /hazmat/Deconstruction_Riverdale_EPA.pdf]
  • [5] TOXICS INFORMATION SERIES: ASBESTOS [PDF], U.S. EPA, April 1980
  • [7] HISTORY OF ASBESTOS IN THE UK - THE STORY SO FAR ..., Silverdell PLC, 14 Buckingham St., London WC2N 6DF TelP 0207 389 6906, email: info@silverdell.plc.uk website: www.silverdell.plc.uk. Web search 3/4/12, original source: issuu.com/silverdell_plc/docs/silverdell_history_of_asbestos_article
  • [12] "Asbestos in your home or at work," Forsyth County Environmental Affairs Department, Winston-Salem NC 12/08
  • [14] ASBESTOS IN YOUR HOME U.S. EPA, Exposure Evaluation Division, Office of Toxic Substances, Office of Pesticides and Toxic Substances, U.S. Environmental Protection Agency, Washington,D.C. 20460
  • [21] Rotterdam Convention PIC, see http://www.pic.int/home.php?type=s&id=77, and for a PDF on the composition of vinyl-asbestos flooring, see http://www.pic.int/en/DGDs/Alternatives/USA/American%20alternatives%20part%203.pdf
    where PIC refers to
    Prior Informed Consent Procedure for Certain Hazardous Chemicals and Pesticides in International Trade on 10 September 1998. 
  • [22] CERAMIC TILE - WHAT IS ASBESTOS ? [PDF] Resource4Mesothelioma, Mesothelioma Information and Legal Guide web search 3/6/2012, original source: resource4mesothelioma.com/topics/whatisasbestos.html and
    also
    CERAMIC TILE ASBESTOS [local copy] original source mesothelioma.com/asbestos-exposure/products/ceramic-tiles.htm
  • [23] ASBESTOS, ITS INDUSTRIAL APPLICATIONS, D.V. Rosato, engineering consultant, Newton, MA, Reinhold Publishing, 1959 Library of Congress Catalog Card No.: 59-12535 [out of print, original copy, text and images provided by InspectAPedia.com (c)].
  • [24] Microwave thermal inertisation of asbestos containing waste and its recycling in traditional ceramics. Leonelli C, Veronesi P, Boccaccini DN, Rivasi MR, Barbieri L, Andreola F, Lancellotti I, Rabitti D, Pellacani GC. Dipartimento di Ingegneria dei Materiali e dell'Ambiente, Università di Modena e Reggio Emilia, Via Vignolese 905, 41100 Modena, Italy. leonelli@unimore.it Journal of Hazardous Materials 135 (1–3): 149–155 - Citation: J Hazard Mater. 2006 Jul 31;135(1-3):149-55. Epub 2006 Jan 10., web search 3/6/2012, original source: http://www.ncbi.nlm.nih.gov/pubmed/16406335

    Abstract: Asbestos was widely used as a building material prior to the 1970's. It is well known that asbestos is a health hazard and its progressive elimination is a priority for pollution prevention. Asbestos can be transformed to non-hazardous silicate phases by microwave thermal treatment.

    The aim of this investigation is to describe the microwave inertization process of asbestos containing waste (ACW) and its recycling in porcelain stoneware tiles, porous single-fired wall tiles and ceramic bricks following industrial manufacture procedure.

    Inertised asbestos powder was added in the percentages of 1, 3, and 5 wt.% to commercially available compositions and then fired following industrial thermal cycles. Water absorption and linear shrinkage of the obtained industrial products do not present significant variations with additions up to 5 wt.% of microwave inertised ACW.
  • [25] ASBESTEOS-CERAMIC, Wikipedia, web search 3/6/2012, original source: http://en.wikipedia.org/wiki/Asbestos-ceramic
  • Thomas Hauswirth, Managing Member of Beacon Fine Home Inspections, LLC and (in 2007) Vice President, Connecticut Association of Home Inspectors Ph. 860-526-3355 Fax 860-526-2942 beaconinspections@sbcglobal.net 06/07: thanks for photographs of transite asbestos heating ducts
  • [26] "History of asbestos discovery and use and asbestos-related disease in context with the occurrence of asbestos within ophiolite complexes", Malcolm Ross, Robert P. Nolan, Geological Society of America, Special Paper, 2003.
    Abstract:

    Two ancient asbestos mines, one near Karystos, Greece and the other southeast of Mount Troodos, Cyprus, were located in what we now know to be ophiolite terrane. Evidence suggests that asbestos was discovered and utilized in Cyprus,perhaps as long as 5000 years ago, for manufacture of cremation cloths, lamp wicks, hats, and shoes.

    Some of the adverse health effects became known only in the early twentieth century, but it was not until the 1960's that the asbestos-related diseases - asbestosis, lung cancer, and mesothelioma - were fully understood.

    Approximately 855 of the world's asbestos was produced from ophiolite complexes, most of which as the chrysotile variety; termolite, actinolite, and anthophyllite asbestos accounting for only a few percent of the total.

    Asbestos minerals crystallize within tectonized ophiolites -along shear, fault, and dilation zones, and at contacts with intruded dikes and sills. Important chrysotile asbestos mines are found in the ophiolites of eastern Canada, the Russian Urals, California, northwest Italy, northern Greece, and Cyprus.

    A high incidence of mesothelioma, a cancer of the lugn lining, is reported among residents of villages located within or near ophiolite complexes in Greece, Turkey, Cyprus, Corsica, and New Caledonia.

    These villages were exposed to tremolite asbestos while processing stucco and whitewash for application to homes. Asbestos contamination in various geographic localities has generated concern about health risks and has prompted costly remediatl actions, especially in the United Kingdom and the United States.

    A scientific basis for public policy is offered to address the utilization of asbestos-bearing rocks.
  • [27] 57 F.Supp. 339 (1965), TILE COUNCIL OF AMERICA, INC., Plaintiff, v. CERAMIC TILERS SUPPLY, INC., Defendant. No. 62-267. United States District Court S. D. California, Central Division. August 13, 1965. Quoting

    "the 392 patent ... It also discloses composition containing the ingredients above mentioned which include sand as well as one which includes asbestos but not sand together with the other ingredients heretofore mentioned. The 382 patent also discloses a method of manufacturing such compositions."
  • [28] "The transformation sequence of cement–asbestos slates up to 1200 °C and safe recycling of the reaction product in stoneware tile mixtures A.F. Gualtieri, C. Cavenati, I. Zanatto, M. Meloni, G. Elmi, M. Lassinantti Gualtier, Journal of Hazardous Materials Volume 152, Issue 2, 1 April 2008, Pages 563–570
    Quoting:

    The material was powdered and studied to see if it is suitable to be recycled in stoneware tile
    mixtures similarly to the protocol used in Gualtieri and Tartaglia [20] "

    " The product of transformation of cement–asbestos (CATP) has a phase composition similar to that of a natural or a low temperature clinker with the exception of having a larger content of aluminium, iron and magnesium.

    This product can be safely recycled for the production of stoneware tile mixtures. The addition of 3–5 mass% of CATP does not bear significant variations to the standard parameters of white porcelain tile mixtures. "
  • [29] "A glass-bonded ceramic material from chrysotile (white asbestos)", K. J. D. Mackenzie and R. H.Meinhold, JOURNAL OF MATERIALS SCIENCE Volume 29, Number 10, 2775-2783, DOI: 10.1007/BF00356832, Abstract:

    A process has been developed for bonding chrysotile asbestos into a robust, dimensionally-stable lightweight ceramic material by fusing it with sodium silicate and/or ground waste glass.

    The chrysotile can retain its desirable properties of fibrous morphology and porosity, but the fibre bundles are stabilized by fusion into a glassy matrix, reducing the respirable fibre concentration.

    The glass-bonded materials have good resistance to mechanical abrasion, and any resulting dust is found by SEM to be particularly free of fibres.

    The thermal treatment also converts the chrysotile into crystalline forsterite, which should destroy its cell toxicity. Other methods of glass-bonding chrysotile compacts (hot pressing and impregnating with glaze) were also investigated, and the properties of the resulting materials are reported.


    Reference Type: Journal Article Author: Mackenzie, K. J. D. Author: Meinhold, R. H. Primary Title: A glass-bonded ceramic material from chrysotile (white asbestos) Journal Name: Journal of Materials Science Cover Date: 1994-01-01 Publisher: Springer Netherlands Issn: 0022-2461 Subject: Chemistry and Materials Science Start Page: 2775 End Page: 2783 Volume: 29 Issue: 10 Url: http://dx.doi.org/10.1007/BF00356832 Doi: 10.1007/BF00356832
  • [30] "Firing transformations of cretaceous clays used in the manufacturing of ceramic tiles", M.M Jordána, Corresponding author contact information, A Boixa, T Sanfeliua, C de la Fuenteb, Applied Clay Science, Volume 14, Issue 4, April 1999, Pages 225–234
  • [31] "Use of granite sawing wastes in the production of ceramic bricks and tiles", Romualdo R. Menezesa, Corresponding author contact information, E-mail the corresponding author, Heber S. Ferreirab, E-mail the corresponding author, Gelmires A. Nevesb, E-mail the corresponding author, Helio de L. Lirab, E-mail the corresponding author, Heber C. Ferreirab, E-mail the corresponding author , Journal of the European Ceramic Society, Volume 25, Issue 7, May 2005, Pages 1149–1158
  • [32] [Chapter 4.4. Clay Masonry Units] of Olin's Construction: Principles, Materials, and Methods, 9th ed., H. Leslie Simmons, John Wiley & Sons 2011, ISBN 978-0-470-54740-3
  • [33] Ceramics - Chemistry Encyclopedia - structure, water, uses, elements, examples, metal, number, salt http://www.chemistryexplained.com/Bo-Ce/Ceramics.html#ixzz1oRox0tMa
  • [34] Books on tile production:
    • Barsoum, Michael W. (1996). Fundamentals of Ceramics. New York: McGraw-Hill.
    • Bender, W. and F. Handle, eds. Brick and Tile Making: Procedures and Operating Practices in the Heavy Clay Industries. Bauverlag GmbH, 1982.
    • Jones, J. T. and M. F. Berard. Ceramics: Industrial Processing and Testing. Iowa State University Press, 1972.
    • Kingery, W. D.; Bowen, H. K.; and Uhlmann, D. R. (1976). Introduction to Ceramics , 2nd edition. New York: Wiley.
    • Pellacani, G. and T. Manfredini. Engineered Materials Handbook. ASM International, 1991, pp. 925-929.
  • [35] Ceramic Tile Institute of America, CTIOA, Tel: 310-574-7800, website: www.ctioa.org/ Email: ctioa@earthlink.net Quote:

    The mission of CTIOA: To promote appropriate and expanded use of ceramic tile and natural stone through education.

    The Ceramic Tile Institute of America Inc. provides manufacturer’s information only.

    The Ceramic Tile Institute of America Inc. does not test the products listed nor do we validate manufacturer’s claims. The Ceramic Tile Institute of America inc. is not responsible for the performance of the products shown on this site.
  • [36] POTENTIAL ASBESTOS HAZARD in ART CLAY, [PDF] Mark K. McQuillan, [letter] Connecticut Department of Public Health, 26 June 2007, CT DOH, Phone: (860) 509-7740 Fax: (860) 509-7785 Telephone Device for the Deaf (860) 509-7191 410 Capitol Avenue - MS # 11EOH P.O. Box 340308 Hartford, CT 06134
    web search 3/8/12 original source: ct.gov/dph/lib/dph/environmental_health/asbestos/pdf/ArtClayLetter.pdf
    [copy on file as: /hazmat/ArtClayLetter.pdf ] Excerpt:

    Talc is added to certain clays as a “flux” to lower the temperature at which the clay needs to be heated. The DPH has become aware that the talc from at least one mine in the Northeast may be contaminated with a type of asbestos called anthophyllite.

    Although there has been debate if the asbestos found in talc actually falls under the regulatory definition of asbestos, there is enough uncertainty to warrant caution when using clays with added talc.

    A recent court case in New Jersey found talc mined by the R.T. Vanderbilt Company of New York was responsible for an asbestos-related cancer ( mesothelioma) in a pottery shop owner. The pottery shop owner had purchased talc (Nytal 100) in large bags and mixed it in clays he used and sold.
  • [37] CPSC and Milton Bradley Co. Recall "Fibro-Clay", US Consumer Product Safety Commission, Release #83-012, March 1983. web seach 3/8/12 original source cpsc.gov/cpscpub/prerel/prhtml83/83012.html [copy on file as /hazamat/FIBRO-CLAY_ Recall.pdf ]
    Excerpt:

    Milton Bradley made Fibro-Clay from 1967 until 1975, when it ceased manufacture of the product. The firm stated that no asbestos has been used in the formula since 1972, and that the quantity sold by its Educational Division was relatively small.
  • [38] US CPSC FOIA Request S606074: Duggan v. Duncan Ceramics, Report 950907CWE7271 and related investigation reports and correspoindence ..., [letter, CPSC to Jennifer N. Willis], 22 July 1997, with attachments, documents, technical articles, [copy on file as /hazmat/CPSC_FOIA_S606074.pdf ]
  • [39] "Precautions for Elementary and Secondary Art Teachers", Ida Herma Williams, Center for Occupational Hazards, [available in op.cit. #37]
  • [40] "Ceramics", Michael McCann, Ph.D., C.I.H., Center for SAFETY in the Arts, 5 Beekman St., New York NY 10038, [undated, available in op.cit.#37]
  • [41] "Art and Craft Safety Guide", US CPSC, Publication #5015, original source: http://www.cpsc.gov/CPSCPUB/PUBS/5015.pdf, [copy on file as /hazmat/CPSC_5015.pdf
  • [42] Asbestos Testing Laboratory Survey, Daniel Friedman (editor), InsapectAPedia.com, March 2012.

    Using the U.S. NIST directory of accredited laboratories certified for asbestos fiber analysis, [http://ts.nist.gov/standards/scopes/plmtm.htm]

    we polled at least one laboratory in each U.S. state, Puerto Rico, two Canadian Provinces, and laboratories in Japan and Korea, asking each if their laboratory had ever received ceramic tiles for asbestos testing and whether or not their lab had ever detected asbestos in ceramic tiles used on walls, floors, or other building services. Results are included above on this page - in this article.
  • [43] "Where can you find asbestos? Floor tiles, textiles, composites", Health and Executive Safety, web search 3/8/12 original source: http://www.hse.gov.uk/asbestos/essentials/floortiles.htm Quoting:

    HSE is the national independent watchdog for work-related health, safety and illness.
    We are an independent regulator and act in the public interest to reduce work-related death and serious injury across Great Britain’s workplaces.
  • [44] International Asbestos Testing Laboratories, Frank E. Ehrenfeld III, Laboratory Director - Vice President, 9000 Commerce Parkway, Suite B, Mount Laurel, NJ 08054, Office: 856 231-9449, psersonal communication, email & telcon: 3/8/2012
  • [45] Handbook of Clay Science, R.E. Grim, Elsevier Science, 2006, ISBN-10: 0080441831 ISBN-13: 978-0080441832[WATCH OUT the price for this book is very high]
  • [46]The Clay Minerals Society 3635 Concorde Pkwy Suite 500, Chantilly, VA 20151-1110, United States, Tel: (703) 652-9960, Email: cms@clays.org website http://www.clays.org/,
  • [47] SEMIQUANTITATIVE CHEMICAL ANALYSIS OF ASBESTOS FIBERS AND CLAY MINERALS WITH AN ANALYTICAL ELECTRON MICROSCOPE [PDF] Hisato Hayashi, Saburo Aita and Mikio Suzuki, Clays and Minerals, Vol. 26. No. 3, pp. 181-188, 1978, web search 3/8/12 original source: clays.org/journal/archive/volume%2026/26-3-181.pdf
  • [48] Sheet silicates (phyllosilicates): clays, micas and serpentine (including chrysotile asbestos), E&ES213: Mineralogy Lecture March 22, Ellen Thomas, Wesleyan University, 45 Wyllys Avenue, Middletown, CT 06459, (860) 685-2000 [copy on file as /hazmat/Clays and asbestos_EThomas_Wesleyan.pdf]

    [Helpful definitions & descriptions of clay & asbestos from an environmental scientist - ed.]
  • [49] Phillip A. Peterson, Vice President, Fibertec Industrial Hygiene Services, Inc., 1914 Holloway Drive Holt, MI 48842, Phone: 517-699-0345, ext. 1, www.fibertec.us. Personal correspondence 3/14/2012 - DJF.
  • [50] Asbestos Program, Michigan Occupational Safety & Health Administration, Michigan Department of Licensing and Regulatory Affairs Michigan Occupational Safety & Health Administration Construction Safety & Health Division - Asbestos Program 7150 Harris Drive P. O. Box 30671 Lansing, Michigan 48909-8171 517.322.1320 (office) 517.322.1713 (fax) E-mail: asbestos@michigan.gov, website:
    http://www.michigan.gov/lara/0,4601,7-154-11407_15333_15369-41708--,00.html
    [4/23/12 requested technical review]
  • In addition to citations & references found in this article, see the research citations given at the end of the related articles found at our suggested

    CONTINUE READING or RECOMMENDED ARTICLES.


ADVERTISEMENT