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Hydrogen Sulfide Gas (H2S)
Odors in Buildings, overlooked sources
POST a QUESTION or COMMENT about often overlooked causes of hydrogen sulfide gas smells or H2S or sewer gas or septic odors in buildings
Hydrogen sulfide (H2S) gas sources in buildings:
Don't overlook these possible sources of sewer gas smells or hydrogen sulfide gas odors: here are the causes, sources, & cures for often overlooked sources of sewer gas smells. This article series explains how to diagnose, find, and cure odors in buildings including septic or sewage or sewer gas smells or "gas odors" in buildings.
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- Daniel Friedman, Publisher/Editor/Author - See WHO ARE WE?
Hydrogen Sulfide or Rotten Egg Smells: building sources, causes, dangers, advice
In addition, exposure to high levels of these gases can be harmful, even fatal, as we detail below.
Because sewer gas contains
methane gas (CH4) there is a risk of an explosion hazard or even fatal asphyxiation.
Sewer gases also probably contain hydrogen sulfide gas (H2S) In addition some writers opine that there are possible
health hazards from sewer gas exposure, such as a bacterial infection of the sinuses (which can occur due to any sinus irritation). Hydrogen is extremely flammable (easily set fire or explodes).
Depending on the sewer gas source and other factors such as humidity and building
and weather conditions, mold spores may also be present in sewer gases.
Sources of Hydrogen sulfide (H2S) or Septic System or Sewer Gas Odors at Buildings
Here are some key places to look:
Batteries:
leaky or failing batteries, such as 12V or 24V car batteries, or batteries used to power a backup sump or sewage pump may produce a sulphur or rotten-egg odor.
Drain waste vent piping clogs or leaks
like the leak shown in our photo at above left. See
Other H2S Odors, sewer-gas-like odors or sulphur odors may be hydrogen sulfide (H2S)
and may occur from these conditions which you may not have considered.
Inspect the building water heater:
if the "sewer gas smell" is noticed particularly when hot water is being run at a sink, tub, or shower, have your plumber check for a bad water heater sacrificial anode.
This rod is intended to slow corrosion in the water heater tank but when the anode deteriorates it can cause a "rotten egg" smell in the hot water supply which may be mistaken for sewer gas.
We discuss the hot water tank sacrificial anode and dip tube in more detail
Watch out: Hydrogen sulfide gas is potentially explosive, can catch fire, and if it is mixed with or originating from sewer gases, it may contain pathogens or be harmful to humans and other animals.
But in addition, water heaters can be a source of this sulphur or rotten egg smell due to bacterial growth or anode deterioration as we just cited. Water heater manufacturers, including American Water Heater Co., advise,
Hydrogen gas is produced in a hot water system served by this heater that has not been used for a long
period of time (2 weeks or more). Hydrogen is extremely flammable.
To reduce the risk of injury under these conditions,
it is recommended that the hot water faucet be opened for several minutes at the kitchen sink before using any electrical
appliance connected to the hot water system.
When hydrogen is present, there will be an unusual sound such as air
escaping through the pipe as the water begins to flow. There should be no smoking or open flame near the faucet at
the time it is open. [5]
More details about dangers of hydrogen sulfide gas exposure are
if the "sewer gas smell" is a "rotten egg smell" and if it is noticed particularly when hot or cold water are being run at a sink, tub, or shower, your water supply
may contain excessive hydrogen sulphide or H2S.
This is not likely to be the case if you are on a municipal or community water supply but could occur if your water is supplied by a private well. Have the water tested
for sulphur and H2S. If this condition is confirmed, the H2S is not a health concern but remains an aesthetic one.
It can be corrected by installation of a proper water treatment system such as a chlorine injection system, a potassium permanganate filtration system, or by other methods. More information about causes of and cures for hydrogen sulfide odors in water is
during well disinfection or for water treatment equipment disinfection involves steps that can produce hydrogen sulfide. Watch out for hydrogen sulfide (H2S) during the mixing procedure.
If there is H2S in the water you will need to aerate the water to dissipate that gas before adding vinegar (or chlorine) to the water.
in the building, or perhaps excessive use of antibiotics (such as by a nursing home served by a septic tank and whose residents consume a lot of antibiotics) can kill off bacteria in the septic tank. This is an unusual condition unlikely to occur in a normal homeowner environment.
Septic system, sewer system, & building drain defects
are common sources of sewer gases and hydrogen sulfide odors in buildings - but not if everything is working properly.
But a loose toilet, blocked plumbing vent, improperly-maintained aerobic septic system, or a failing septic drainfield can be a source of sewer gas odors observed both indoors and outside.
Watch out: both hydrogen sulfide gas and methane gas (both present in sewer gases) are potentially explosive. Hydrogen sulfide gas is heavier than air, poisonous, corrosive, flammable (will burn), and depending on its concentration in air, it can explode.
My older sister Linda and later my best friend David Hoff both led experiments in attempts to light ... well, politely put, human flatulence gases.
Results were amazing. But in buildings, an accumulation of hydrogen sulfide gas H2S is not funny, it is potentially catastrophic, or fatal should an explosion occur. In dangerous mixtures with air or if put into direct contact with nitric acid, H2S explodes. (Fletcher 1999)
Compound is heavier than air and may travel a considerable distance to source of ignition and flash back.
Hydrogen sulfide forms explosive mixtures with air over a wide range. Also reacts explosively with bromine pentafluoride, chlorine trifluoride, nitrogen triiodide, nitrogen trichloride, oxygen difluoride, and phenyl diazonium chloride.
When heated to decomposition,
Hydrogen sulfide emits highly toxic fumes of oxides of sulfur. Incompatible with many materials including strong oxidizers, metals, strong nitric acid, bromine pentafluoride, chlorine trifluoride, nitrogen triiodide, nitrogen trichloride, oxygen difluoride and phenyl diazonium chloride.
Avoid physical damage to containers; sources of ignition; storage near nitric acid, strong oxidizing materials, and corrosive liquids or gases. (Chemcial Book, Hydrogen Sulfide CAS No. 7783-06-04)
Hydrogen Sulfide Gas H2S Exposure Dangers
The following information about hydrogen sulfide gas H2S hazards is adapted from information from U.S. Army Field Manual 8-285 Chapter 10, Noxious Chemicals:
10-4. Hydrogen Sulfide Gas Danger Information
Physical Properties of Hydrogen Sulfide Gas:
This colorless gas in low
concentrations has the odor of rotten eggs. In high
concentrations it may dull the sense of smell and be
difficult to recognize.
Occurrence of hydrogen sulfide gas in military operations. This gas is
produced during the decomposition of sulfur containing
compounds in sewers, waste, coal bins or
stacks, holds of ships, and waterfront excavations.
Occurrence of hydrogen sulfide gas in Military Operations as well as in civilian and residential conditions
Hydrogen sulfide gas is
produced during the decomposition of sulfur containing
compounds in sewers, waste, coal bins
Pathology of Hydrogen Sulfide Gas Exposure
In low concentrations (less than
0.15 mg per liter), hydrogen sulfide may produce
inflammation of the eyes, nose, and throat if breathed
for periods of 1/2 to 1 hour.
Watch out: higher concentrations of hydrogen sulfide (H2S) gas (0.75 mg per liter or greater) are rapidly fatal, presumably by combination of the hydrogen sulfide with
the respiratory tissue pigments and the subsequent
paralysis of the respiratory center.
Symptoms of Hydrogen Sulfide Gas Exposure
The symptoms depend upon the
concentration of the gas. At the lowest concentrations,
the effects are chiefly on the eyes; that is,
conjunctivitis, swollen eyelids, itchiness, smarting,
pain, photophobia, and blurring of vision. At higher
concentrations, respiratory tract symptoms are more pronounced.
Rhinitis, pharyngitis, laryngitis, and
bronchitis may occur. Pulmonary edema may result.
At very high concentrations, unconsciousness, convulsions,
and cessation of respiration rapidly develop.
Details about H2S exposure effects & limits are at
Immediately remove the casualty
from the contaminated atmosphere and administer
assisted ventilation with oxygen, if possible. Treatment
of pulmonary edema is the same as for that
caused by CG (chap 5).
Reader Comment: Hydrogen Sulfide Gas H2S health hazards warning & citation of HUD Dictionary of Deficiency Definitions
Not a question just a comment.
HUD regulates how to keep those in living in subsidized housing from the dangers of sewer gas inhalation but the state of Georgia (Georgia Dept. of Community Affairs a HUD area housing administrator) does not follow that HUD mandate and that is why myself and my child have severe lung disease that is caused from our prolonged exposure to sewer gas within and about a Bremen, GA rental.
See page 305
Sewer Odor Detected (Air Quality) quoted below:
Deficiency:
You detect sewer odors that could pose a health risk if inhaled for prolonged periods.
- SB4Justice - 4/4/2013
Reply:
SB4Justice
Thanks I've posted your remark above so that I could include a link to
Also below in our references we include citations [3][4][5][6][7][8] describing the health hazards of breathing hydrogen sulfide gas H2S, and of course methane can be a more immediate hazard - that of explosion.
Details about Hydrogen Sulfide gas and advice about tracking down such odors are on this page in the article above.
Details about methane gas hazards are given separately
Watch out: while H2S can be dangerous, readers should keep in mind that both H2S and more commonly methane gas (a significant component in sewer gas) is dangerously explosive and at sufficient concentrations can also be fatal. So both can be an immediate hazard, not just a health hazard.
The same HUD Deficiencies document you cite, back up on page 304 also warns:
Propane/Natural Gas/Methane Gas Detected (Air Quality)
Deficiency: You detect strong propane, natural gas, or methane gas odors that could:
pose a risk of explosion/fire
pose a health risk if inhaled
And from HUD Pass/Fail deficiencies p. 302 we have more general advice
Air Quality (Health and Safety)
Indoor/Outdoor spaces must be free from high levels of sewer gas, fuel gas, mold,
mildew, or other harmful pollutants. Indoors must have adequate ventilation.
The following deficiencies can be noted:
Mold and/or Mildew Observed
Propane/Natural Gas/Methane Gas Detected
Sewer Odor Detected
Which is in error only that mildew is never found in buildings, only mold, unless the mildew is growing on a plant (my photo at left).
Mildew is an obligate parasite that only grows on plants. Of course normal people don't know that and the word "mildew" is used by lay persons interchangeably (if incorrectly) with "mold".
On 2019-09-02 by Jared Raymer - house inundated with sewer gas (H2S) for 4 months
My Mother has a house that was inundated with sewer gas (H2S) for a period of about 4 months. There is still some kind of smell that is in the house years later. Do you know of any ways to treat this house to keep items in the house from off gassing? like seal the walls and repaint?
Is there any way to know that this house is safe to live in?
The house was aired out after the incident happed. There was a ozoneator also ran in the house for a long period of time.
There is proof that the H2S was there due to the copper wiring in the walls by the outlets turning black and silver. Any advice on this problem would be greatly appreciated. Thanks, Jared
On 2019-09-03 by (mod) -
Jared
Before prescribing a "cure" for the indoor odor AND before deciding if the house is safe to live-in, it would be best to
1. Identify the odor source - so that removal, cleaning, or sealing are effectively focused - See the ARTILE INDEX to find
2. Have the property's electrical and mechanical systems inspected for corrosion that could make electrical wiring, controls, or HVAC equipment unsafe - as H2S may have caused harmful corrosion: put safety ahead even of odor mitigation
See this example of such damage:
CHINESE DRYWALL HAZARDS where other links will suggest further investigation and mitigation.
On 2017-09-02 by Pamela Pawlowski - What does hydrogen sulfide smell like
What does hydrogen sulfide smell like
On 2017-09-02 by (mod)
Hydrogen sulfide gas or H2S smells like Rotten eggs
On 2017-07-25 by ray scott - flickering lights, lost electrical power, then rotten egg smell
We had a bad rain during the night when we woke up several lights were flickering and power to bathroom went off.
An electrician was called and he found the copper wire in a light fixture to be not connected tight. He fixed the problem and the lights started working. several hours later returned home to have a strong rotten egg smell in several rooms of the house.
Don't know what caused this. Any comments on problem. Thanks
On 2017-07-26 by (mod) -
Not sure what would be the connection, Ray, but to be very safe you could turn off that circuit on the theory that a wire or component may be overheating.
Then see if you can track down where the odor is strongest - that'd be diagnostic.
Odors of sewage or sulphur often are due to a drain backup or septic failure that might show up in wet weather.
On 2017-03-27 by Smithe438 - compliment
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On 2017-03-27 by (mod) -
Thank you, SmithE. Assuming you're not kidding me, I'll add that we work hard to provide researched, unbiased data so I'm happy when a reader finds our information useful.
WATER ODORS, CAUSE CURE - home: follow this link to correct sulphur odors in the water supply coming from a well or from contamianted hot water heater tanks or similar sources
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In addition to any citations in the article above, a full list is available on request.
"HydrogenSulfide", United States Department of Labor, OSHA, reference, retrieved 2/2/2014, original source: https://www.osha.gov/dts/chemicalsampling/data/CH_246800.html
Hydrogen Sulfide (H2S) - OSHA Fact Sheet, United States Department of Labor, OSHA, reference, retrieved 2/2/2014, original source: https://www.osha.gov/OshDoc/data_Hurricane_Facts/hydrogen_sulfide_fact.pdf
Lyn E. Fletcher, Potential Explosive Hazards from Hydrogen Sulfide Production in Ship Ballast and Sewage Tanks [PDF] Maritime Platforms Division
Aeronautical and Maritime Research Laboratory DSTO-TR-0750, (1999) Commonwealth of Australia, Department of Defence, Defence Science and Technology Organisation, retrieved 2/2/2014, original source: www.dtic.mil/cgi-bin/GetTRDoc?AD=ADA360622
ABSTRACT -
Hydrogen sulfide produced by sulfate-reducing bacteria is a well recognised toxic
hazard in storage tanks on HMA Ships, however, it also has the potential to be an
explosive hazard. Hydrogen sulfide can cause explosions when its concentration
exceeds 4% in air. A number of storage tanks on HMA Ships theoretically have the
potential to produce enough hydrogen sulfide to exceed this figure.
This report
assesses the likelihood of this occurring in ballast and sewage holding tanks. Sewage
tanks pose the greatest risk of an explosive hazard occurring and this situation is
exacerbated when seawater is used for flushing or a concentrated sewage is produced
due to reduced flushing volumes, as is the situation with EVAC systems. Ballast tanks
that contain only seawater and Deiso F76 pose minimal risk, but any contamination of
the tanks with biodegradable material would increase this risk considerably.
Glass, D. C. "A review of the health effects of hydrogen sulphide exposure." Annals of Occupational Hygiene 34, no. 3 (1990): 323-327.
Glass, D. C. "A review of the health effects of hydrogen sulphide exposure." Annals of Occupational Hygiene 34, no. 3 (1990): 323-327.
[1] Thanks to Slade Franklin
for the reminder that a leaky wax ring at a toilet can lead to septic odors in bathrooms. 11/2007
[2] Thanks to J.V. (privacy protected) for the reminder to make a detailed inspection of the plumbing vent system when sewer gas odors are present. 07/2008
[3] Thanks to Roger Hankey & Cheryll Brown, www.hankeyandbrown.com, ASHI home inspectors in Minnesota, for the deteriorated transite pipe gas flue vent photograph and comments. Mr. Hankey is a past chairman of the ASHI Technical Committee, serves as co-chairman of ASHI legislative committee, and has served in other ASHI professional and leadership roles. 7/2007.
[5] "Residential Electric Water Heater Installation Instructions and Use & Care Guide", American Water Heater Co., October 2001, American Water Heater Co., Johnson City, TN, [manufacturer of residential & commercial water heaters, also manufacturer of Polaris/Commercial water heaters], Tel: 800-999-9515, web search 1/12/2012, original source: americanwaterheater.com/support/manuals/res-elect.pdf [copy on file]
Amoore, J.E. and Hautala, E., 1983. Odor as an aid to chemical safety: odor thresholds compared with threshold limit values and volatilities for 214 industrial chemicals in air and water dilution. Journal of Applied Toxicology 3, 272-290.
Bates, M.N., Garrett, N. and Shoemack, P., 2002. Investigation of health effects of hydrogen sulfide from a geothermal source. Archives of Environmental Health, 57(5): 405-411.
[6] Gangolli, S. (Ed.), 1999. The Dictionary of Substances and their Effects, 2nd edn. The Royal Society of Chemistry. Cambridge.
[7] Sax, N.I. and Lewis, R.J., Sr., 1989. Dangerous Properties of Industrial Materials, 7th edn. Van Nostrand Reinhold. New York.
[8] Snyder, J.W., Safir, E.F., Summerville, G.P. and Middleberg, R.A., 1995. Occupational fatality and persistent neurological sequelae after mass exposure to hydrogen sulfide. American Journal of Emergency Medicine, 13(2): 199-203.
Amoore, J.E. and Hautala, E., 1983. Odor as an aid to chemical safety: odor thresholds compared with threshold limit values and volatilities for 214 industrial chemicals in air and water dilution. Journal of Applied Toxicology 3, 272-290.
Bates, M.N., Garrett, N. and Shoemack, P., 2002. Investigation of health effects of hydrogen sulfide from a geothermal source. Archives of Environmental Health, 57(5): 405-411.
Gangolli, S. (Ed.), 1999. The Dictionary of Substances and their Effects, 2nd edn. The Royal Society of Chemistry. Cambridge.
Sax, N.I. and Lewis, R.J., Sr., 1989. Dangerous Properties of Industrial Materials, 7th edn. Van Nostrand Reinhold. New York.
Snyder, J.W., Safir, E.F., Summerville, G.P. and Middleberg, R.A., 1995. Occupational fatality and persistent neurological sequelae after mass exposure to hydrogen sulfide. American Journal of Emergency Medicine, 13(2): 199-203.
Septic Tank/Soil-Absorption Systems: How to Operate & Maintain [ copy on file as /septic/Septic_Operation_USDA.pdf ] - , Equipment Tips, U.S. Department of Agriculture, 8271 1302, 7100 Engineering, 2300 Recreation, September 1982, web search 08/28/2010, original source: http://www.fs.fed.us/t-d/pubs/pdfimage/82711302.pdf.
Pennsylvania State Fact Sheets relating to domestic wastewater treatment systems include
Pennsylvania State Wastewater Treatment Fact Sheet SW-161, Septic System Failure: Diagnosis and Treatment
Pennsylvania State Wastewater Treatment Fact Sheet SW-162, The Soil Media and the Percolation Test
Pennsylvania State Wastewater Treatment Fact Sheet SW-l64, Mound Systems for Wastewater Treatment
Pennsylvania State Wastewater Treatment Fact Sheet SW-165, Septic Tank-Soil Absorption Systems
Document Sources used for this web page include but are not limited to: Agricultural Fact Sheet #SW-161 "Septic Tank Pumping," by Paul D. Robillard and
Kelli S. Martin. Penn State College of Agriculture - Cooperative Extension, edited and annotated by
Dan Friedman (Thanks: to Bob Mackey for proofreading the original source material.)
In addition to citations & references found in this article, see the research citations given at the end of the related articles found at our suggested
Carson, Dunlop & Associates Ltd., 120 Carlton Street Suite 407, Toronto ON M5A 4K2. Tel: (416) 964-9415 1-800-268-7070 Email: info@carsondunlop.com. Alan Carson is a past president of ASHI, the American Society of Home Inspectors.
Carson Dunlop Associates provides extensive home inspection education and report writing material. In gratitude we provide links to tsome Carson Dunlop Associates products and services.